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Samsung Chromebook Plus XE513C24
Developer Mode
Turn off the laptop.
To invoke Recovery mode, you hold down the ESC and Refresh keys and poke the Power button.
At the Recovery screen press Ctrl-D (there's no prompt - you have to know to do it).
Confirm switching to developer mode by pressing enter, and the laptop will reboot and reset the system. This takes about 10-15 minutes.
Note: After enabling developer mode, you will need to press Ctrl-D each time you boot, or wait 30 seconds to continue booting.
Enable booting from external storage
After booting into developer mode, hold Ctrl and Alt and poke the T key. This will open up the crosh shell.
Type shell to get into a bash shell.
Type sudo -i to become root. (sudo su doesn't seem to be available and this is functionally the same)
Then type this to enable USB booting:
crossystem dev_boot_usb=1 dev_boot_signed_only=0
First Attempt Gentoo SD Image
Refrences